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World Journal of Advance Healthcare Research (WJAHR) is giving Best Article Award in every Issue for Best Article and Issue Certificate of Appreciation to the Authors to promote research activity of scholar.
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Abstract
PALM OIL, COTTON OIL ESTERIFICATION, A KINETIC STUDY
Heba Huthaifa Naseef*, Seba Ahmad Naseef and Reem Hani Tulaimat
ABSTRACT
Elevated economic and environmental concerns have spurred the exploration of vegetable oils for biodiesel production, offering a greener alternative to conventional fossil diesel. With inherent fatty acid content vital for yield enhancement, this research delves into the kinetics of fatty acid esterification within a blend of (palm/cotton) oil. The investigation encompasses varied methanol molar ratios at different temperatures, Employing sulfuric acid as a catalyst with concentrations precisely designated at 5 wt% and 10 wt%. Optimal conditions include a methanol-to-oil molar ratio of 3:1, a 10% catalyst concentration, and a temperature of 60°C, resulting in a more efficient reaction time. Furthermore, This study rigorously evaluated physical and chemical properties, including acid value, FFA%, viscosity, and density, for both the oil blend and each of its components. A proposed kinetic model, employing the initial rates method, determined a rate constant of (2.3×10^(-3) Lit/mol.min) for the direct esterification reaction. Exploration of temperature's impact on the rate constant, utilizing the Arrhenius equation, revealed an activation energy (Ea) of 95.7357 kJ/mol. These comprehensive findings not only optimize the biodiesel production process but also underscore the importance of sustainable practices in shaping a cleaner and more efficient energy landscape.
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